Ligand-dependent stereoselective Suzuki–Miyaura cross-coupling reactions of β-enamido triflates

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F21%3A00548519" target="_blank" >RIV/61388963:_____/21:00548519 - isvavai.cz</a>
Alternative codes found
RIV/00216208:11310/21:10436938
Result on the web
<a href="https://doi.org/10.3762/bjoc.17.179" target="_blank" >https://doi.org/10.3762/bjoc.17.179</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.3762/bjoc.17.179" target="_blank" >10.3762/bjoc.17.179</a>

Result language
angličtina
Original language name
Ligand-dependent stereoselective Suzuki–Miyaura cross-coupling reactions of β-enamido triflates
Original language description
The stereoselective Suzuki–Miyaura cross-coupling of (Z)-β-enamido triflates is demonstrated. Depending on the nature of the ligand in the palladium catalyst, either retention or inversion of the configuration during the synthesis of β,β-diaryl-substituted enamides is observed. Thus, the method provides synthetic access to both isomers of the target enamides from (Z)-β-enamido triflates.
Czech name
—
Czech description
—

Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10401 - Organic chemistry

Project
<a href="/en/project/LTAUSA18037" target="_blank" >LTAUSA18037: Synthesis and reactivity of N-fluoroalkylated compounds</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)