New chiral ECD-Raman spectroscopy of atropisomeric naphthalenediimides

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F22%3A00556557" target="_blank" >RIV/61388963:_____/22:00556557 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1039/D1CC06974H" target="_blank" >https://doi.org/10.1039/D1CC06974H</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/d1cc06974h" target="_blank" >10.1039/d1cc06974h</a>

Result language
angličtina
Original language name
New chiral ECD-Raman spectroscopy of atropisomeric naphthalenediimides
Original language description
In this study, we found that a recently discovered ECD-Raman effect dominated over the natural Raman optical activity in a series of atropisomeric naphthalenediimides, and we investigated the kind of information about the molecular structure that could be obtained from the spectra. The ECD-Raman effect is polarised Raman scattering modulated by electronic circular dichroism. We showed that the spectra significantly depended on the substitution of the solute and/or the change of the solvent. Moreover, the spectra could be well-predicted by the theory, thus providing an interesting tool to monitor the chirality of the binaphthyl compounds.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2022
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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