Resolving Resonant Electronic States in Chiral Metal Complexes by Raman Optical Activity Spectroscopy

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F22%3A00557361" target="_blank" >RIV/61388963:_____/22:00557361 - isvavai.cz</a>

Alternative codes found

RIV/61989592:15310/22:73613058

Result on the web

<a href="https://doi.org/10.1021/acs.jpclett.2c00653" target="_blank" >https://doi.org/10.1021/acs.jpclett.2c00653</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1021/acs.jpclett.2c00653" target="_blank" >10.1021/acs.jpclett.2c00653</a>

Result language

angličtina

Original language name

Resolving Resonant Electronic States in Chiral Metal Complexes by Raman Optical Activity Spectroscopy

Original language description

Chiral metal complexes exhibit rich photophysical properties and are important for applications ranging from biosensing to photocatalysis. We present a combined experimental and computational approach leading to information about energies and transition moments of excited electronic states, documented on two chiral metal complexes. The experimental protocol for measurement of the resonance Raman optical activity comprises multiple techniques, i.e., absorption, circular dichroism, and polarized and differential Raman scattering. An accurate formula for subtraction of the interfering circular dichroism/polarized Raman scattering effect is given. An analysis of the spectra based on density functional theory calculations unveils the geometric and electronic structures of the molecules. Such insight into molecular electronic states of chromophores may be useful for understanding and tuning photochemical properties of metal-containing complexes, biomolecules, and supramolecules.

Czech name

—

Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

—

OECD FORD branch

10403 - Physical chemistry

Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2022

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Physical Chemistry Letters

ISSN

1948-7185

e-ISSN

—

Volume of the periodical

13

Issue of the periodical within the volume

17

Country of publishing house

US - UNITED STATES

Number of pages

5

Pages from-to

3873-3877

UT code for WoS article

000799352500014

EID of the result in the Scopus database

2-s2.0-85129242050