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Resolving Resonant Electronic States in Chiral Metal Complexes by Raman Optical Activity Spectroscopy

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F22%3A00557361" target="_blank" >RIV/61388963:_____/22:00557361 - isvavai.cz</a>

  • Alternative codes found

    RIV/61989592:15310/22:73613058

  • Result on the web

    <a href="https://doi.org/10.1021/acs.jpclett.2c00653" target="_blank" >https://doi.org/10.1021/acs.jpclett.2c00653</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1021/acs.jpclett.2c00653" target="_blank" >10.1021/acs.jpclett.2c00653</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Resolving Resonant Electronic States in Chiral Metal Complexes by Raman Optical Activity Spectroscopy

  • Original language description

    Chiral metal complexes exhibit rich photophysical properties and are important for applications ranging from biosensing to photocatalysis. We present a combined experimental and computational approach leading to information about energies and transition moments of excited electronic states, documented on two chiral metal complexes. The experimental protocol for measurement of the resonance Raman optical activity comprises multiple techniques, i.e., absorption, circular dichroism, and polarized and differential Raman scattering. An accurate formula for subtraction of the interfering circular dichroism/polarized Raman scattering effect is given. An analysis of the spectra based on density functional theory calculations unveils the geometric and electronic structures of the molecules. Such insight into molecular electronic states of chromophores may be useful for understanding and tuning photochemical properties of metal-containing complexes, biomolecules, and supramolecules.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10403 - Physical chemistry

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2022

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Physical Chemistry Letters

  • ISSN

    1948-7185

  • e-ISSN

  • Volume of the periodical

    13

  • Issue of the periodical within the volume

    17

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    5

  • Pages from-to

    3873-3877

  • UT code for WoS article

    000799352500014

  • EID of the result in the Scopus database

    2-s2.0-85129242050