Regular arrays of C60-based molecular rotors mounted on the surface of tris(o-phenylenedioxy)cyclotriphosphazene nanocrystals

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F24%3A00581813" target="_blank" >RIV/61388963:_____/24:00581813 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1039/D3CC04559E" target="_blank" >https://doi.org/10.1039/D3CC04559E</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/d3cc04559e" target="_blank" >10.1039/d3cc04559e</a>

Result language
angličtina
Original language name
Regular arrays of C60-based molecular rotors mounted on the surface of tris(o-phenylenedioxy)cyclotriphosphazene nanocrystals
Original language description
Dielectric spectroscopy has been used to determine the barriers of rotation of surface-mounted fullerenes (2.3 +/- 0.1 and 4.3 +/- 0.1 kcal mol(-1)). In order to achieve this, a C-60 derivative equipped with an anchoring group designed to form a surface inclusion with the hexagonal form of tris(o-phenylenedioxy)cyclotriphosphazene (TPP) has been synthesized. Solid-state NMR analysis revealed that approximately 50% of the surface-mounted molecules have a chemical environment different from the others suggesting two distinct insertion modes. These observations correlate with results of DFT calculations.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2024
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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