Lewis acid-mediated transformations of 5-acyl-N-fluoroalkyl-1,2,3-triazoles to cyclopentenones, indenones, or oxazoles

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F24%3A00585622" target="_blank" >RIV/61388963:_____/24:00585622 - isvavai.cz</a>
Alternative codes found
RIV/00216208:11310/24:10483628
Result on the web
<a href="https://doi.org/10.1039/D4RA01707B" target="_blank" >https://doi.org/10.1039/D4RA01707B</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/d4ra01707b" target="_blank" >10.1039/d4ra01707b</a>

Result language
angličtina
Original language name
Lewis acid-mediated transformations of 5-acyl-N-fluoroalkyl-1,2,3-triazoles to cyclopentenones, indenones, or oxazoles
Original language description
We present a transition metal-free approach to 2-N-substituted indenones, cyclopentenones, and 4-carbonyl oxazoles, based on the reaction of 5-acylated N-fluoroalkyl substituted 1,2,3-triazoles (prepared by a three-component click reaction of copper acetylides, fluoroalkyl azides, and acyl chlorides) with Lewis acids aluminium trichloride or boron trifluoride etherate, proceeding via the generation and cyclization of vinyl cations.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10401 - Organic chemistry

Project
<a href="/en/project/GA23-04659S" target="_blank" >GA23-04659S: Utilization of organic fluorinated azides for the synthesis of unusual nitrogen heterocycles</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2024
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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