Vibrational Analysis Based on Cavity-Enhanced Raman Spectroscopy: Cyclohexane

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388963%3A_____%2F25%3A00618903" target="_blank" >RIV/61388963:_____/25:00618903 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1021/acs.jpca.4c07709" target="_blank" >https://doi.org/10.1021/acs.jpca.4c07709</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.jpca.4c07709" target="_blank" >10.1021/acs.jpca.4c07709</a>

Result language
angličtina
Original language name
Vibrational Analysis Based on Cavity-Enhanced Raman Spectroscopy: Cyclohexane
Original language description
Cyclohexane (CAS: 110-82-7), a colorless organic solvent derived from petroleum, is a valuable reference standard for Raman shift calibration and serves as a model for six-membered ring structures in complex chemical and biological systems. In this study, we measured polarized Raman spectra of gaseous cyclohexane at room temperature using cavity-enhanced Raman spectroscopy (CERS) across the range of 200-3200 cm-1. The observed vibrational wavenumbers, intensities, and depolarization ratios were compared with calculated values, enabling the assignment of several dozen Raman-active bands, including many overtone and combination bands. This work demonstrates the capability of CERS for vibrational analysis of gas-phase polyatomic molecules.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10403 - Physical chemistry

Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2025
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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