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ABNOH-Linked Nucleotides and DNA for Bioconjugation and Cross-linking with Tryptophan-Containing Peptides and Proteins

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388971%3A_____%2F24%3A00587190" target="_blank" >RIV/61388971:_____/24:00587190 - isvavai.cz</a>

  • Alternative codes found

    RIV/61388963:_____/24:00587190 RIV/00216208:11310/24:10495136

  • Result on the web

    <a href="https://doi.org/10.1002/chem.202402151" target="_blank" >https://doi.org/10.1002/chem.202402151</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/chem.202402151" target="_blank" >10.1002/chem.202402151</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    ABNOH-Linked Nucleotides and DNA for Bioconjugation and Cross-linking with Tryptophan-Containing Peptides and Proteins

  • Original language description

    Reactive N-hydroxy-9-azabicyclo[3.3.1]nonane (ABNOH) linked 2’-deoxyuridine 5’-O-mono- and triphosphates were synthesized through a CuAAC click reaction of ABNO-H-PEG4-N3 with 5-ethynyl-dUMP or -dUTP. The modified triphosphate was used as substrate for enzymatic synthesis of modified DNA probes with KOD XL DNA polymerase. The keto-ABNO radical reacted with tryptophan (Trp) and Trp-containing peptides to form a stable 3-fused hexahydropyrrolo-indole conjugates. Similarly modified ABNO-H-linked nucleotides reacted with Trp-containing peptides to form a stable conjugate in the presence but surprisingly even in the absence of NaNO2 (presumably through activation by O2). The reactive ABNO-H-modified DNA probe was used for bioconjugations and crosslinking with Trp-containing peptides or proteins.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10608 - Biochemistry and molecular biology

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2024

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Chemistry - A European Journal

  • ISSN

    0947-6539

  • e-ISSN

    1521-3765

  • Volume of the periodical

    30

  • Issue of the periodical within the volume

    49

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    9

  • Pages from-to

    e202402151

  • UT code for WoS article

    001289658400001

  • EID of the result in the Scopus database

    2-s2.0-85200955670