Recent developments in the chemistry of the nine-vertex monocarbaboranes.

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F02%3A50023011" target="_blank" >RIV/61388980:_____/02:50023011 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Recent developments in the chemistry of the nine-vertex monocarbaboranes.

Original language description

A short review is presented on the routes to the synthesis of the nine-vertex monocarbaboranes arachno-4-CB8H14 and nido-1-CB8H12 12, which now have become very important starting materials for the preparation of a family of 'smaller-cage' seven-, eight-, and nine-vertex closo monocarbaborane anions [2-CB6H7](-), [1-CB7H8](-), and [4-CB8H9](-). These anions exhibit high stability and have a good chance to become new candidates for weakly coordinated anion chemistry. Discussed are also reactions leadingnew families of phosphamonocarbaboranes that contain one, two, and three phosphorus atoms in the cage. These compounds, namely closo-2,1-PCB8H9, closo-6,1-PCB8H9, nido-7,8,9-P2CB8H10, and nido-6,7,8,9,10-P3CB7H8, are structural analogues of the corresponding carboranes and are likely to exhibit similar chemical behavior. (C) 2002 Elsevier Science B.V. All rights reserved.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2002

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Organometallic Chemistry

ISSN

0022-328X

e-ISSN

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Volume of the periodical

657

Issue of the periodical within the volume

1-2

Country of publishing house

CH - SWITZERLAND

Number of pages

6

Pages from-to

3-8

UT code for WoS article

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EID of the result in the Scopus database

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