New carboranes and phosphaboranes.

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F03%3A50033023" target="_blank" >RIV/61388980:_____/03:50033023 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
New carboranes and phosphaboranes.
Original language description
A review is presented on the new routes to the synthesis of the monocarbaboranes [arachno-6-CB9H14](-), arachno-4-CB8H14, and nido-1-CB8H12, that now have become excellent starting materials for the preparation of a family of seven-, eight-, and nine-vertex closo-monocarbaborane anions [2-CB6H7](-), [1-CB7H8](-), and [4-CB8H9](-). These anions exhibit hi-h stability and have a good chance to become new candidates for weakly coordinated anion chemistry. Discussed are also reactions leading new families of phosphacarboranes that contain one, two, and three phosphorus atoms in the cage. These compounds, namely closo-2,1-PCB8H9, closo-6,1-PCB8H9, nido-7,8,9-PC2B8H11, nido-7,8,11-PC2B8H11, and nido-7,8,9,10-P3CB7H8, are structural analogs of the corresponding carboranes and are likely to exhibit similar chemical behavior.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2003
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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