Voltammetric measurement of the Pt electrode capacity and the determination of the polyvalent ions diffusion coefficients in the glass melt.
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F03%3A50033031" target="_blank" >RIV/61388980:_____/03:50033031 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Voltammetric measurement of the Pt electrode capacity and the determination of the polyvalent ions diffusion coefficients in the glass melt.
Original language description
The cyclic voltammetry has been used to investigate the kinetic behaviour of polyvalent ions in a silicate glass melt within a temperature range from 900 to 1300degreesC. Standard potentials of oxidation-reduction reactions of the polyvalent elements present in glass melt as refining or colouring agents (Fe and Cr) were measured. Diffusion coefficients of Fe3- and Cr3- ions in the melt were calculated from the shape of cyclic voltammograms. Their values were found from 10(-9) to 10(-7) cm(2) s(-1) respectively. Double layer capacity (480 mu F/cm(2)) measured in the basic glass without of polyvalent elements corresponds to the high concentration of ions in the melt.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/IAA4032002" target="_blank" >IAA4032002: The Preparation and Propeerties of Aprotic Gel Polymer Electrolytes</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2003
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Ceramics-Silikaty
ISSN
0862-5468
e-ISSN
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Volume of the periodical
47
Issue of the periodical within the volume
2
Country of publishing house
CZ - CZECH REPUBLIC
Number of pages
5
Pages from-to
51-55
UT code for WoS article
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EID of the result in the Scopus database
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