Diferratricarbaboranes of the subcloso-[eta(5)-C5H5)(2)Fe2C3B8H11] type, the first representatives of the 13-vertex dimetallatricarbaborane series.

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F03%3A50033041" target="_blank" >RIV/61388980:_____/03:50033041 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Diferratricarbaboranes of the subcloso-[eta(5)-C5H5)(2)Fe2C3B8H11] type, the first representatives of the 13-vertex dimetallatricarbaborane series.

Original language description

Treatment of the [2-Cp-9tBuNH-closo-2,1,7,9-FeC3B8H10] (1) ferratricarbollide (Cp = eta(5)-C5H5-) with Na+C10H8- in 1,2-dimethoxy-ethane (DME) at room temperature produced an air-sensitive transient anion with a tentatively identified nido-[tBuNH-CpFeC3B8H10](2-) constitution. In-situ reaction of this low-stability ion with [CpFe(CO)(2)I] or [CpFe(CO)(2)](2) generated three violet di-ferratricarbaboranes identified as paramagnetic subcloso complexes [4,5-Cp2--4,5,1,6,7-Fe2C3B8H11] (2; yield 2%), [4,5-CP2--4,5,1,7,12-Fe2C3B8H11] (3; yield 2%), and [7-tBuNH-4,5-Cp2-- 4,5,1,7,12-Fe2C3B8H10] (4; yield 14%). These first representatives of the 13-vertex dimetallatricarbaborane family were characterized by EPR and IR spectroscopy, and mass spectrometry, and their structures were determined by X-ray diffraction analysis.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2003

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Chemistry A European Journal

ISSN

0947-6539

e-ISSN

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Volume of the periodical

9

Issue of the periodical within the volume

24

Country of publishing house

DE - GERMANY

Number of pages

7

Pages from-to

6115-6121

UT code for WoS article

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EID of the result in the Scopus database

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