Metal complexes with an amino substituted tricarbollide ligand

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F05%3A00021493" target="_blank" >RIV/61388980:_____/05:00021493 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Metal complexes with an amino substituted tricarbollide ligand
Original language description
The reaction of the tricarbollide salt Tl[7-tBuNH-7,8,9-C3B8H10] (Tl1) with [(cod)Rh(THF)(x)](+) gives the rhodium complex [1(cod)-12-tBuNH-1,2,4,12-RhC3B8H10] in almost quantitative yield. Analogous reactions of Tl1 with [(ring)M(THF)(x)](2+) ((ring)M =Cp*Rh and (1,3,5-C6H3Me3)Ru) afford the corresponding metallatricarbollides [1-(ring)-12-tBuNH-1,2,4,12-MC3B8H10] in ca. 50% yield. Refluxing Tl1 with [Mn(CO)(3)(MeCN)(3)](+) in THF give the tricarbollide analogue of eymantrene, [1,1,1-(CO)(3)-12-tBuNH-1,2,4,12-MnC3B8H10], the structure of which was determined by single-crystal X-ray diffraction analysis. In all cases, the formation of the metallatricarbollide complexes is accompanied by polyhedral rearrangement leading to the maximum separation of thecage carbon atoms.
Czech name
Kovové komplexy s aminosubstituovanými tricarbollidovými ligandy
Czech description
Reakce of the trikarbollidové sloučeniny Tl[7-tBuNH-7,8,9-C3B8H10] s různými organokovovými kationty vedla k serii nových trikarbollidových komplexů obsahujících Rh, Ru a Mn jako centrální kovový atom.

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/GA203%2F05%2F2646" target="_blank" >GA203/05/2646: Derivatization of ferratricarbollide</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2005
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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