Cyclopentadienyl ruthenium comlexes with tricarbolide ligands

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F10%3A00354532" target="_blank" >RIV/61388980:_____/10:00354532 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Cyclopentadienyl ruthenium comlexes with tricarbolide ligands

Original language description

Reaction of the tricarbollide anion [7,8,9-C3B8H11](-) (1a) with the naphthalene complex [CpRu(C10H8)](+) under visible light irradiation in CH2Cl2 gives the 12-vertex closo-rthenacarborane 1-Cp-1,2,3,5-RuC3B8H11 (2; 87% yield). This complex was also obtained by reaction of 1a with CpRu(cod) Cl (97%). Upon heating at 80 C in toluene 2 rearranges into isomer 1-Cp-1,2,4,10-RuC3B8H11 (3; 63%). Irradiation of 1a with [CpRu(C10H8)](+) in acetone gives the 11-vertex closo-1-Cp-1,2,3,4-RuC3B7H10 (4; 32%). Thelatter was also prepared by reaction of 1a with [CpRu(MeCN)(3)]+ (59%). Compound 2 slowly undergoes cage contraction in acetone giving 4.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

<a href="/en/project/LC523" target="_blank" >LC523: Perspective inorganic materials</a><br>

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2010

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Collection of Czechoslovak Chemical Communications

ISSN

0010-0765

e-ISSN

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Volume of the periodical

75

Issue of the periodical within the volume

11

Country of publishing house

CZ - CZECH REPUBLIC

Number of pages

10

Pages from-to

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UT code for WoS article

000284230500006

EID of the result in the Scopus database

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