Ferra- and ruthenatricarbollides CpFeC3B8H11 and Cp*RuC3B8H11

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F05%3A00028598" target="_blank" >RIV/61388980:_____/05:00028598 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Ferra- and ruthenatricarbollides CpFeC3B8H11 and Cp*RuC3B8H11
Original language description
The room-temperature photochemical reaction of the tricarbollide anion [nido-7,8,9-C3B8H11](-) (1a) with [CpFe(C6H6)](+) proceeds without cluster rearrangement to form the 12-vertex closo-ferratricarbollide 1-Cp-1,2,3,4-FeC3B8H11 (2a, the metal atom is assigned number 1). 2a rearranges to the isomeric complex 1-Cp-1,2,3,5-FeC3B8H11 (2b) at 110 degrees C and further to 1-Cp-1,2,4,10-FeC3B8H11 (2c) at 165 degrees C. The reaction of 1a with [Cp*RuCl](4) is accompanied by polyhedral rearrangement giving 1-Cp*-1,2,3,5-RuC3B8H11 (3b). The constitution of the compounds prepared was determined by multinuclear NMR spectroscopy and mass spectrometry. The structures of 2a, 2b, and 3c were established by X-ray diffraction.
Czech name
Ferra a ruthenatrikarbollidy CpFeC3B8H11 a Cp*RuC3B8H11
Czech description
Ferra a ruthenatrikarbollidy CpFeC3B8H11 a Cp*RuC3B8H11byly připraveny insercí fragmentů CpFe+ a CpRu+ do skeletu trikarbaboranového aniontu [nido-7,8,9- C3B8H11]- . Je popsán i vznik několika isomerů lišících se polohou uhlíkových atomů ve skeletu.

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/GA203%2F05%2F2646" target="_blank" >GA203/05/2646: Derivatization of ferratricarbollide</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2005
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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