The first (tricarbollide)rhodium halide complexes

Result code in IS VaVaI

RIV/61388980:_____/11:00358361 - isvavai.cz

Result on the web

http://dx.doi.org/10.1016/j.inoche.2010.11.024

DOI - Digital Object Identifier

10.1016/j.inoche.2010.11.024

Result language

angličtina

Original language name

The first (tricarbollide)rhodium halide complexes

Original language description

Reactions of (eta-1-(BuNH)-Bu-t-1,7,9-C3B8H10)Rh(cod) with Br-2 or I-2 give complexes [(eta-1-(BuNH)-Bu-t-1,7.9-C3B8H10) RhX2](2) (X=Br (2a), I (2b)). Reaction of 2b with TIBF4 affords cation [(eta-1-(BuNH)-Bu-t-1,7.9-C3B8H10)(2)Rh-2(mu-I)(3)](+) (3). Complex 2a reacts with Tl[Tl(eta-7,8-C2B9H11)] giving the bis(carborane) complex (eta-1-(BuNH)-Bu-t-1,7,9-C3B8H10)Rh (eta-7,8-C2B9H11) (4). Structures of 2a,b were determined by X-ray diffraction.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

LC523: Perspective inorganic materials

Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2011

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Inorganic Chemistry Communications

ISSN

1387-7003

e-ISSN

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Volume of the periodical

14

Issue of the periodical within the volume

1

Country of publishing house

NL - THE KINGDOM OF THE NETHERLANDS

Number of pages

3

Pages from-to

313-315

UT code for WoS article

000287269000081

EID of the result in the Scopus database

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