The first (tricarbollide)rhodium halide complexes

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F11%3A00358361" target="_blank" >RIV/61388980:_____/11:00358361 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.inoche.2010.11.024" target="_blank" >http://dx.doi.org/10.1016/j.inoche.2010.11.024</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.inoche.2010.11.024" target="_blank" >10.1016/j.inoche.2010.11.024</a>

Result language
angličtina
Original language name
The first (tricarbollide)rhodium halide complexes
Original language description
Reactions of (eta-1-(BuNH)-Bu-t-1,7,9-C3B8H10)Rh(cod) with Br-2 or I-2 give complexes [(eta-1-(BuNH)-Bu-t-1,7.9-C3B8H10) RhX2](2) (X=Br (2a), I (2b)). Reaction of 2b with TIBF4 affords cation [(eta-1-(BuNH)-Bu-t-1,7.9-C3B8H10)(2)Rh-2(mu-I)(3)](+) (3). Complex 2a reacts with Tl[Tl(eta-7,8-C2B9H11)] giving the bis(carborane) complex (eta-1-(BuNH)-Bu-t-1,7,9-C3B8H10)Rh (eta-7,8-C2B9H11) (4). Structures of 2a,b were determined by X-ray diffraction.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/LC523" target="_blank" >LC523: Perspective inorganic materials</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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