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The first metallacarborane triple-decker complexes with a bridging pentaphospholyl ligand

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F10%3A00356240" target="_blank" >RIV/61388980:_____/10:00356240 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    The first metallacarborane triple-decker complexes with a bridging pentaphospholyl ligand

  • Original language description

    Visible light irradiation of cations [(Carb)Fe(eta-C6H6)](+) in the presence of Cp*Fe(eta-cyclo-P-5) affords the mu-pentaphospholyl triple-decker complexes [(Carb)Fe(mu-eta:eta-cyclo-P-5)FeCp*](+) (Carb = 9-SMe2-7,8-C2B9H10 (3a) and 1-t-BuNH-1,7,9-C3B8H10 (3b)). Structures of 3a- and 3b[Co(eta-7,8-C2B9H11)(2)] were determined by X-ray diffraction. Bonding in 3a, 3b and mononuclear building blocks was analyzed by energy decomposition analysis.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/LC523" target="_blank" >LC523: Perspective inorganic materials</a><br>

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2010

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Collection of Czechoslovak Chemical Communications

  • ISSN

    0010-0765

  • e-ISSN

  • Volume of the periodical

    75

  • Issue of the periodical within the volume

    9

  • Country of publishing house

    CZ - CZECH REPUBLIC

  • Number of pages

    13

  • Pages from-to

  • UT code for WoS article

    000282524200007

  • EID of the result in the Scopus database