The Synthesis of (.eta.5-cyclopentadienyl)Titanium(IV) Alkoxides by Alcoholysis of the Ti- .pí.-Ligand Bond in Permethyl .eta.3:.eta.4-Allyldiene-(.eta.5-cyclopentadienyl)Titanium(II).

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388955%3A_____%2F03%3A54030092" target="_blank" >RIV/61388955:_____/03:54030092 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
The Synthesis of (.eta.5-cyclopentadienyl)Titanium(IV) Alkoxides by Alcoholysis of the Ti- .pí.-Ligand Bond in Permethyl .eta.3:.eta.4-Allyldiene-(.eta.5-cyclopentadienyl)Titanium(II).
Original language description
The .eta.3:.eta.4-allyldiene-(.eta.5-cyclopentadienyl)titanium(II) complex [Ti(.eta.5-C5Me5) {.eta3:.eta.4-C5Me3(CH2)2}] (I) reacts with three molar equivalents of substituted propargylic alcohols FcC=CCMe2(OH) (2a) and PhC=CCH2OH (2b) at elevated temperature to give (.eta.5-pentamethylcyclopentadienyl)titanium(IV) alkoxides [Ti(.eta.5-C5Me5)(FcC=CCMe2-kO)3] (3a) and [Ti(.eta.5-C5Me5)(PhC=CCH2O-kO)3] (3b), respectively. The crystal structure of 3a has been determined by single-crystal X-ray diffraction.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Project
<a href="/en/project/GA203%2F99%2FM037" target="_blank" >GA203/99/M037: Centre of molecular and crystal structures</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2003
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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