Monocarbaborane chemistry: Cage opening of nido-1-CB8H12 by tertiary bases - an example of a straightforward nido -> arachno transformation; Isolation of a new series of 4-L-arachno-5-CB8H12 compounds (L = NMe3, NEt3, and quinoline)

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F04%3A00106539" target="_blank" >RIV/61388980:_____/04:00106539 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Monocarbaborane chemistry: Cage opening of nido-1-CB8H12 by tertiary bases - an example of a straightforward nido -> arachno transformation; Isolation of a new series of 4-L-arachno-5-CB8H12 compounds (L = NMe3, NEt3, and quinoline)
Original language description
Room-temperature reactions between the carborane nido-1-CB8H12 (1) and selected tertiary Lewis bases [L = NMe3, NEt3, and quinoline (quin)] in CH2Cl2 at room temperature for 24 h resulted in the isolation of a series of 4-L-arachno-5-CB8H12 compounds (2;L = NMe3, 2a, L = NEt3, 2b and L = quin, 2c).
Czech name
Chemie monokarbaboranů: Otevření skeletu nido-1-CB8H12 terciárními basemi- příklad přímé nido-arachno přeměny. Isolace nové serie sloučenin 4-L-arachno-5-CB8H12 (L = NMe3, NEt3 a chinolin)
Czech description
Při normální teplotě reaguje karboran nido-1-CB8H12 terciárními basemi (L = NMe3, NEt3 a chinolin) za vzniku sloučenin 4-L-arachno-5-CB8H12.

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/LN00A028" target="_blank" >LN00A028: New inorganic compounds and advanced materials</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2004
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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