Support effects in nerol hydrogenation over Pt/SiO2, Pt/H-Y and Pt/H-MCM-41 catalysts

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F04%3A00108178" target="_blank" >RIV/61388980:_____/04:00108178 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Support effects in nerol hydrogenation over Pt/SiO2, Pt/H-Y and Pt/H-MCM-41 catalysts
Original language description
Chemoselective hydrogenation of nerol was investigated over Pt/SiO2, Pt/H-Y and Pt/H-MCM-41 catalysts. The initial total reaction rates decreased in following order: Pt/H-Y > Pt/SiO2 > Pt/H-MCM-41. Nerol hydrogenation was found to be an apparent structure sensitive reaction. The selectivities to citronellol at 30% conversion of nerol were 65%, 55% and 25% over Pt/SiO2, Pt/H-MCM-41 and Pt/H-Y, respectively.
Czech name
Vliv nosiče na hydrogenaci nerolu na Pt/SiO2, Pt/H-Y a Pt/H-MCM-41 katalyzátorech
Czech description
Hydrogenace nerolu patří mezi reakce, které výrazně závisí na struktuře hydrogenované látky a na vlastnostech nosiče Pt katalyzátoru. Selektivita hydrogenace vzhledem k tvorbě citronellolu se měnila od 25% do 65% v závislosti na použitém nosiči.

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/GA104%2F03%2F0409" target="_blank" >GA104/03/0409: Asymmetric and regioselective catalytic hydrogenations over Ru catalysts</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2004
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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