Macropolyhedral boron-containing cluster chemistry. Cluster opening and B-frame rearrangement in the reaction of B16H20 with [{(IrCl2(eta(5)-C5Me5)}(2)]. Synchrotron X-ray structures of [(eta(5)-C5Me5)(2)Ir2B16H17Cl] and [(eta(5)-C5Me5)(2)Ir2B16H15Cl]

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F06%3A00050894" target="_blank" >RIV/61388980:_____/06:00050894 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Macropolyhedral boron-containing cluster chemistry. Cluster opening and B-frame rearrangement in the reaction of B16H20 with [{(IrCl2(eta(5)-C5Me5)}(2)]. Synchrotron X-ray structures of [(eta(5)-C5Me5)(2)Ir2B16H17Cl] and [(eta(5)-C5Me5)(2)Ir2B16H15Cl]

Original language description

Products from the reaction of + nido ten- vertex : nido eight-vertex, B16H20 1 with [{( IrCl2(eta(5)- C5Me5)} (2)] and tmnd show unanticipated rearrangement of the starting {B-16} skeleton, as exhibited by + nido ten- vertex : nido ten- vertex, [(eta(5)-C5Me5) (2) Ir2B16H17Cl] 2 which has a {B-2} edge conjunction and by + nido ten- vertex : nido eleven- vertex, [(eta(5)- C5Me5) 2Ir2B16H15Cl] 3 which has a {B-3} face conjunction.

Czech name

Macropolyedrická borová klastrová chemie. Otevření klastru a přesmyk B-skeletu při reakci B16H20 s [{(IrCl2(eta(5)-C5Me5)}(2)].Synchrotronové rentgenové struktury [(eta(5)-C5Me5)(2)Ir2B16H17Cl] a [(eta(5)-C5Me5)(2)Ir2B16H15Cl]

Czech description

Macropolyedrická borová klastrová chemie. Otevření klastru a přesmyk B-skeletu při reakci B16H20 s [{(IrCl2(eta(5)-C5Me5)}(2)]. Synchrotronové rentgenové struktury [(eta(5)-C5Me5)(2)Ir2B16H17Cl] a [(eta(5)- C5Me5)(2)Ir2B16H15Cl].

Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2006

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Dalton Transactions

ISSN

1477-9226

e-ISSN

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Volume of the periodical

44

Issue of the periodical within the volume

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Country of publishing house

GB - UNITED KINGDOM

Number of pages

5

Pages from-to

5221-5224

UT code for WoS article

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EID of the result in the Scopus database

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