Macropolyhedral boron-containing cluster chemistry. Ligand-induced two-electron variations of intercluster bonding intimacy. Structures of nineteen-vertex[(eta(5)-C5Me5) HIrB18H19(PMe2Ph)] and the related carbene complex [(eta(5)-C5Me5)HIrB18H19{C(NHM...

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F04%3A00108166" target="_blank" >RIV/61388980:_____/04:00108166 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Macropolyhedral boron-containing cluster chemistry. Ligand-induced two-electron variations of intercluster bonding intimacy. Structures of nineteen-vertex[(eta(5)-C5Me5) HIrB18H19(PMe2Ph)] and the related carbene complex [(eta(5)-C5Me5)HIrB18H19{C(NHM...
Original language description
Addition of PMe2Ph to fused-cluster syn-[(eta(5)-C5Me5)IrB18H20] 1 to give [(eta(5)-C5Me5) HIrB18H19(PMe2Ph)] 3 entails a diminution in the degree of intimacy of the intercluster fusion, rather than retention of inter-subcluster binding intimacy and a nido --> arachno conversion of the character of either of the subclusters. Reaction with MeNC gives [(eta(5)-C5Me5) HIrB18H19{C(NHMe)(2)}] 4 which has a similar structure, but with the ligand now being the carbene {: C(NHMe)(2)}, resulting from a reductiveassembly reaction involving two MeNC residues and the loss of a carbon atom.
Czech name
Makropolyedrická borová chemie. Dvouelektronové variace intraklastrové vazebné intimity indukované ligandem.. Struktury 19-vrcholového ... a podobného karbenového komplexu
Czech description
Popsána je příprava a genese dvou nových sloučenin v 19-vrcholové iridaboranové řadě.

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Project
<a href="/en/project/IAA4032701" target="_blank" >IAA4032701: Fused-Cage Macropolyhedra Boranes, Carboranes, Heteroboranes, and Metallaheteroboranes.</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2004
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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