Macropolyhedral boron-containing cluster chemistry: two-electron variations in intercluster bonding intimacy. Contrasting structures of 19-vertex [(eta(5)-C5Me5)HIrB18H19(PHPh2)] and [(eta(5) -C5Me5)IrB18H18(PH2Ph)]

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F04%3A00341103" target="_blank" >RIV/61388980:_____/04:00341103 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Macropolyhedral boron-containing cluster chemistry: two-electron variations in intercluster bonding intimacy. Contrasting structures of 19-vertex [(eta(5)-C5Me5)HIrB18H19(PHPh2)] and [(eta(5) -C5Me5)IrB18H18(PH2Ph)]

Original language description

Fused double-cluster [(eta(5)-C5Me5)IrB18H18(PH2Ph)] (8), from syn-[(eta(5)-C5Me5)IrB18H20] (1) and PH2Ph, retains the three-atoms-in-common cluster fusion intimacy of 1, in contrast to [(mu(5)-C5Me5)HIrB18H19(PHPh2)] (6), from PHPh2 with 1, which exhibits an opening to a two atoms-in-common cluster fusion intimacy. Compound 8 forms via spontaneous dihydrogen loss from its precursor [(eta(5)-C5Me5)HIrB18H19(PH2Ph)] (7), which has two-atoms-in-common cluster-fusion intimacy and is structurally analogousto 6.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CA - Inorganic chemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2004

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Inorganica chimica acta

ISSN

0020-1693

e-ISSN

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Volume of the periodical

357

Issue of the periodical within the volume

10

Country of publishing house

NL - THE KINGDOM OF THE NETHERLANDS

Number of pages

6

Pages from-to

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UT code for WoS article

000223116900041

EID of the result in the Scopus database

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