Macropolyhedral boron-containing cluster chemistry [S2B16H17](-). A new eighteen-vertex thiaborane anion
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F10%3A00357559" target="_blank" >RIV/61388980:_____/10:00357559 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Macropolyhedral boron-containing cluster chemistry [S2B16H17](-). A new eighteen-vertex thiaborane anion
Original language description
The novel eighteen-vertex macropolyhedral dithiaborane anion [S2B16H17](-) 1 has been obtained as its [tmndH](+) salt from the reaction of [S2B17H17] 2 and tmnd in solution in the presence of [RhCl2(eta(5)-C5Me5)](2). It has two cluster skeletal electrons more than the three previously reported eighteen-vertex dithiaborane {S2B16} species n-[S2B16H16], n-[S2B16H15](-) and iso-[S2B16H16], and the anion consists structurally of an arachno {SB9} and a nido {B-9} cluster unit fused with two boron atoms in common, and with an endo-to-exo sulfur bridge that also links the two subclusters together.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2010
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Collection of Czechoslovak Chemical Communications
ISSN
0010-0765
e-ISSN
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Volume of the periodical
75
Issue of the periodical within the volume
8
Country of publishing house
CZ - CZECH REPUBLIC
Number of pages
6
Pages from-to
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UT code for WoS article
000281958400003
EID of the result in the Scopus database
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