Expanding Luminescence Horizons in Macropolyhedral Heteroboranes
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F24%3A00584537" target="_blank" >RIV/68378271:_____/24:00584537 - isvavai.cz</a>
Alternative codes found
RIV/61388980:_____/24:00584537
Result on the web
<a href="https://hdl.handle.net/11104/0353212" target="_blank" >https://hdl.handle.net/11104/0353212</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/anie.202401872" target="_blank" >10.1002/anie.202401872</a>
Alternative languages
Result language
angličtina
Original language name
Expanding Luminescence Horizons in Macropolyhedral Heteroboranes
Original language description
Luminescence is observed in three novel macropolyhedral nineteen- and eighteen-vertex chalcogenaboranes: Se2B17H17 (1), SeB17H19 (3) and SeB18H20 (4). This led us to the recognition that previously published macropolyhedral heteroborane species might also exhibit luminescence. Thus, the known nineteen- and eighteen-vertex dithiaboranes S2B17H17 (2), n-S2B16H16 (5) and i-S2B16H16 (6) were synthesised and also found to exhibit a range of luminescent properties. These macropolyhedral species are very different from the previously unique fluorescent binary borane B18H22 in terms of their structural architectures, by the presence of borane cluster hetero atoms, and, as in the cases of 5 and 6, that their synthetic origins are not derived simply through the modification of B18H22 itself. They consequently greatly expand the possibilities of finding new luminescent inorganic borane species.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10302 - Condensed matter physics (including formerly solid state physics, supercond.)
Result continuities
Project
<a href="/en/project/GA23-07563S" target="_blank" >GA23-07563S: Boranes: A route to the inertial confinement of proton-boron fusion.</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2024
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Angewandte Chemie - International Edition
ISSN
1433-7851
e-ISSN
1521-3773
Volume of the periodical
63
Issue of the periodical within the volume
17
Country of publishing house
DE - GERMANY
Number of pages
7
Pages from-to
e202401872
UT code for WoS article
001184688200001
EID of the result in the Scopus database
2-s2.0-85187701610