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The effect of refluxing on the alkoxide-based sodium potassium niobate sol-gel system: Thermal and spectroscopic studies

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61388980%3A_____%2F11%3A00372273" target="_blank" >RIV/61388980:_____/11:00372273 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1016/j.jssc.2010.12.002" target="_blank" >http://dx.doi.org/10.1016/j.jssc.2010.12.002</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.jssc.2010.12.002" target="_blank" >10.1016/j.jssc.2010.12.002</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    The effect of refluxing on the alkoxide-based sodium potassium niobate sol-gel system: Thermal and spectroscopic studies

  • Original language description

    A study on the effects of prolonged heating under reflux conditions of up to 70 h on alkoxides of sodium, potassium and niobium dissolved in 2-methoxyethanol for the synthesis of sols of composition Na(0.5)K(0.5)NbO(3)(NKN) has been carried out using combined thermogravimetric-Fourier transform infrared Spectroscopic analyses. Extended refluxing increases the homogeneity of the Na(0.5)K(0.5)NbO(3) (NKN) system. Spectroscopic analyses on the non-refluxed and 70 h refluxed NKN gels reveal the existence ofinorganic hydrated carbonates and bicarbonates, which we propose arise from the hydration and carbonation of the samples on standing in air. The X-ray diffraction patterns of these two types of gels show orthorhombic NKN phase evolutions at higher temperatures.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CA - Inorganic chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2011

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Solid State Chemistry

  • ISSN

    0022-4596

  • e-ISSN

  • Volume of the periodical

    184

  • Issue of the periodical within the volume

    2

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    8

  • Pages from-to

    317-324

  • UT code for WoS article

    000287268900013

  • EID of the result in the Scopus database