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The potential of Cu(I)Cl/2,2'-bipyridine catalysis in a triblock copolymer preparation by atom transfer radical polymerization.

Result description

Well defined monodisperse copolymer samples, poly(styrene-graft-tert butyl acrylate) and poly(4-methylstyrene-graft-tert-butyl acrylate), were prepared by tertbutylacrylate(tBuA)ATRP grafting from the respective linear monodisperse poly(styrene) or poly(4-methylstyrene) macroinitiators, carrying 40% of suitable haloalkyl initiating functions in the chains. Molecular weights of the copolymers increased linearly with tBuA conversion and were in accord with theoretical values.

Keywords

atom transfer radical polymerizationtriblock copolymerssequential synthesis

The result's identifiers

Alternative languages

  • Result language

    angličtina

  • Original language name

    The potential of Cu(I)Cl/2,2'-bipyridine catalysis in a triblock copolymer preparation by atom transfer radical polymerization.

  • Original language description

    Well defined monodisperse copolymer samples, poly(styrene-graft-tert butyl acrylate) and poly(4-methylstyrene-graft-tert-butyl acrylate), were prepared by tertbutylacrylate(tBuA)ATRP grafting from the respective linear monodisperse poly(styrene) or poly(4-methylstyrene) macroinitiators, carrying 40% of suitable haloalkyl initiating functions in the chains. Molecular weights of the copolymers increased linearly with tBuA conversion and were in accord with theoretical values.

  • Czech name

  • Czech description

Classification

  • Type

    Jx - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CD - Macromolecular chemistry

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2001

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Applied Polymer Science

  • ISSN

    0021-8995

  • e-ISSN

  • Volume of the periodical

    81

  • Issue of the periodical within the volume

    14

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    9

  • Pages from-to

    3514-3522

  • UT code for WoS article

  • EID of the result in the Scopus database