The potential of Cu(I)Cl/2,2'-bipyridine catalysis in a triblock copolymer preparation by atom transfer radical polymerization.
Result description
Well defined monodisperse copolymer samples, poly(styrene-graft-tert butyl acrylate) and poly(4-methylstyrene-graft-tert-butyl acrylate), were prepared by tertbutylacrylate(tBuA)ATRP grafting from the respective linear monodisperse poly(styrene) or poly(4-methylstyrene) macroinitiators, carrying 40% of suitable haloalkyl initiating functions in the chains. Molecular weights of the copolymers increased linearly with tBuA conversion and were in accord with theoretical values.
Keywords
atom transfer radical polymerizationtriblock copolymerssequential synthesis
The result's identifiers
Result code in IS VaVaI
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
The potential of Cu(I)Cl/2,2'-bipyridine catalysis in a triblock copolymer preparation by atom transfer radical polymerization.
Original language description
Well defined monodisperse copolymer samples, poly(styrene-graft-tert butyl acrylate) and poly(4-methylstyrene-graft-tert-butyl acrylate), were prepared by tertbutylacrylate(tBuA)ATRP grafting from the respective linear monodisperse poly(styrene) or poly(4-methylstyrene) macroinitiators, carrying 40% of suitable haloalkyl initiating functions in the chains. Molecular weights of the copolymers increased linearly with tBuA conversion and were in accord with theoretical values.
Czech name
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Czech description
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Classification
Type
Jx - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CD - Macromolecular chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2001
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Applied Polymer Science
ISSN
0021-8995
e-ISSN
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Volume of the periodical
81
Issue of the periodical within the volume
14
Country of publishing house
US - UNITED STATES
Number of pages
9
Pages from-to
3514-3522
UT code for WoS article
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EID of the result in the Scopus database
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Basic information
Result type
Jx - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP
CD - Macromolecular chemistry
Year of implementation
2001