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Time-resolved luminescence of terbium complexes with poly(2- and 4-vinylpyridine N-oxide)s in aqueous solution

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F04%3A00101317" target="_blank" >RIV/61389013:_____/04:00101317 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Time-resolved luminescence of terbium complexes with poly(2- and 4-vinylpyridine N-oxide)s in aqueous solution

  • Original language description

    Terbium complexes with polymer ligands of poly(2- and 4-vinylpyridine N-oxide)s (P2VPNO, P4VPNO) in aqueous solution were prepared and characterized. Multi-exponential decays of terbium transition at 545 nm of [P2VPNO-Tb(III)] and [P4VPNO-Tb(III)] were measured. The non-linearity of semilogarithmic plots of time-resolved luminescence was more pronounced with P4VPNO than with P2VPNO, being reduced by addition of salts as sodium formate or acetate.

  • Czech name

    Časově rozlišená luminescence komplexů terbia s poly(2- a 4-vinylpyridiny N-oxidy) ve vodných roztocích

  • Czech description

    Komplexy terbia s polymerními ligandy poly(2- a 4-vinylpyridin N-oxidu) byly připraveny a charakterizovány ve vodném roztoku. Byly změřeny multiexponenciální rozpady terbia při 545 nm v [P2VPNO-Tb(III)] a [P4VPNO-Tb(III)] komplexech. Nelinearita semilogaritmických výnosů časově rozlišené luminiscence je větší u P4VPNO než u P2VPNO a je redukována přídavkem solí jako mravenčanem nebo octanem sodným.

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CD - Macromolecular chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA203%2F01%2F0512" target="_blank" >GA203/01/0512: Luminiscent lanthanide complexes with polymer ligands</a><br>

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2004

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Macromolecular Symposia

  • ISSN

    1022-1360

  • e-ISSN

  • Volume of the periodical

    212

  • Issue of the periodical within the volume

    1

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    6

  • Pages from-to

    239-244

  • UT code for WoS article

  • EID of the result in the Scopus database