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Solid polymer electrolytes studied by NMR spectroscopy and DFT calculations

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F06%3A00031499" target="_blank" >RIV/61389013:_____/06:00031499 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Solid polymer electrolytes studied by NMR spectroscopy and DFT calculations

  • Original language description

    Results obtained recently on polymer electrolytes poly(ethylene oxide) /LiCF3SO3 and poly(2-ethyl-2-oxazoline)/AgCF3SO3 by a combination of solid-state 13C and 1H NMR spectroscopy and DFT quantum-chemical calculations are discussed. Essentially the samelocal structure was found for the amorphous and crystalline phases of semicrystalline PEO/LiCF3SO3 polymer electrolyte. A close contact between the metal salt and polymer was determined for both investigated systems from the Lee-Goldburg cross-polarization 1H 13C dynamics

  • Czech name

    Polymerní elektrolyty v pevném stavu studované NMR spektroskopií a DFT výpočty

  • Czech description

    Jsou diskutovány výsledky nedávno získané na polymerních elektrolytech polyetylenoxid (PEO)/LiCF3SO3 a poly(2-etyl-2-oxazolin)/AgCF3SO3 kombinací 13C a 1H NMR spektroskopie pevného stavu a DFT kvantově-chemických výpočtů. Pro amorfní a krystalickou fázisemikrystalického polymerního elektrolytu PEO/LiCF3SO3 byla zjištěna v podstatě stejná lokální struktura. Z dynamiky Lee-Goldburg křížové polarizace 1H-13C pro oba zkoumané systémy vyplynulo, že sůl kovu a polymer jsou v těsném kontaktu.

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CD - Macromolecular chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA525%2F05%2F0273" target="_blank" >GA525/05/0273: Study of beta -glucans of particular edible mushrooms</a><br>

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2006

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Macromolecular Symposia

  • ISSN

    1022-1360

  • e-ISSN

  • Volume of the periodical

    235

  • Issue of the periodical within the volume

    1

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    7

  • Pages from-to

    57-63

  • UT code for WoS article

  • EID of the result in the Scopus database