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Combined experimental and theoretical study on the complexation of H3O+ with hexaethyl calix[6]arene hexaacetate

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F07%3A00080915" target="_blank" >RIV/61389013:_____/07:00080915 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Combined experimental and theoretical study on the complexation of H3O+ with hexaethyl calix[6]arene hexaacetate

  • Original language description

    By using quantum mechanical DFT calculations, the most probable structure of the 1.H3O+ complex species was predicted. In this complex, the hydroxonium ion H3O+ is bound partly to three carbonyl oxygen atoms by strong hydrogen bonds and partly to three alternate phenoxy oxygens by somewhat weaker hydrogen bonds.

  • Czech name

    Experimentální a teoretické studium komplexace H3O+ s hexaethyl calix[6]arene hexaacetate

  • Czech description

    Pomocí kvantově chemických DFT výpočtů byla stanovena nejpravděpodobnější struktura komplexu H3O+ s hexaethyl calix[6]arene hexaacetate. V tomto komplexu je hydroxoniový ion vázán ke třem karbonylovým atomům kyslíku silnými vodíkovými vazbami a ke třem fenoxylovým atomům kyslíku poněkud slabšími vodíkovými vazbami.

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CD - Macromolecular chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/1ET400500402" target="_blank" >1ET400500402: Computer modelling of chmical structures for the design of macromolecular systems with new biological, mechanical and electronic properties</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2007

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Zeitschrift für Physikalische Chemie : International Journal of Research in Physical Chemistry & Chemical Physics

  • ISSN

    0942-9352

  • e-ISSN

  • Volume of the periodical

    221

  • Issue of the periodical within the volume

    4

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    7

  • Pages from-to

    519-525

  • UT code for WoS article

  • EID of the result in the Scopus database