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Synthesis of amphiphilic copolymers by ATRP initiated with a bifunctional initiator containing trichlomethyl groups

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F07%3A00086791" target="_blank" >RIV/61389013:_____/07:00086791 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Synthesis of amphiphilic copolymers by ATRP initiated with a bifunctional initiator containing trichlomethyl groups

  • Original language description

    Bifunctional initiators with trichloromethyl active groups were successfully used to synthesize polystyrene homopolymers and a styrene/HEMA random copolymer using ATRP catalyzed with CuCl in the presence of amine-type ligands. With both the ligands, HMTETA or PMDETA, the ATRP proceeds in a "living" manner, giving polystyrenes with narrow MWDs and Mn, which are near to the theoretical values.

  • Czech name

    Syntéza amfifilních kopolymerů pomocí ATRP iniciované bifunkčním iniciátorem nesoucím trichloromethylové skupiny

  • Czech description

    Bifunkční iniciátor obsahující trichloromethylové skupiny byl použit jako iniciátor pro syntézu polystyrenů a statistických kopolymerů styren/HEMA pomocí ATRP, katalyzované komplexem CuCl s amínovými ligandy. ATRP probíhá kontrolovaným způsobem jak s HMTETA tak s PMDETA, což dokládají úzké MWD připravených polystyrenů a rovněž jejich Mn blízká teoretické hodnotě.

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CD - Macromolecular chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/1P05ME753" target="_blank" >1P05ME753: Preparation , characterisation and application of gradient polymer layers on solid substrates</a><br>

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2007

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Reactive and Functional Polymers

  • ISSN

    1381-5148

  • e-ISSN

  • Volume of the periodical

    67

  • Issue of the periodical within the volume

    10

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    13

  • Pages from-to

    1027-1039

  • UT code for WoS article

  • EID of the result in the Scopus database