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Compatibilization of PP/PE blends and scraps with Royalene: Mechanical properties, SAXS, and WAXS

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F08%3A00306725" target="_blank" >RIV/61389013:_____/08:00306725 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Compatibilization of PP/PE blends and scraps with Royalene: Mechanical properties, SAXS, and WAXS

  • Original language description

    PP/PE 93/7 model virgin blends and recycled scraps were compatibilized with Royalene (EPDM/PE 65/35 blend) and mechanically tested. No differences in impact and tensile properties between them were found. However, the tensile-impact strength increased almost twice with 10%-compatibilized sample in comparison with uncompatibilized ones. The yield stress of blends containing 10% Royalene decreased to 75-80% of the original value. The elongation at break and elongation at yield do not depend on the compatibilizer concentration. The compatibilizer does not influence the degree of crystallinity (WAXS data) of the blends either. Vickers microhardness is in good agreement with Tabor's relationship. The differences between long periods of HDPE in Royalene andLDPE in PP/PE blends proved PE/EPDM interaction. The interaction plays a key role in the toughening of PP/PE blends.

  • Czech name

    Kompatibilizace směsí a recyklátů PP/PE s přídavkem Royalene: Mechanické vlastnosti, SAXS a WAXS

  • Czech description

    Modelové a recyklované směsi PP/PE 93/7 byly kompatibilizovány přídavkem Royalene (směs EPDM/PE 65/35) a mechanicky testovány. Nebyly nalezeny rozdíly v houževnatosti a pevnosti mezi modelovými směsmi a recykláty. Kompatibilizací (10%) se houževnatost zvyšuje téměř dvakrát, mez kluzu se snižuje na 75-80%,což koreluje s hodnotami mikrotvrdosti. Tažnost, deformace na mezi kluzu ani krystalinita nezávisí na koncentraci kompatibilizátoru. Naměřená Vickersova mikrotvrdost dobře vyhovuje Taborovu vztahu. Rozdíly v hodnotách dlouhé periody HDPE v Royalenu a LDPE ve směsích PP/PE dokazují interakci mezi PE a EPDM, jež je klíčová pro zvýšení houževnatosti směsí PP/PE.

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    CD - Macromolecular chemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/2B06097" target="_blank" >2B06097: Complex recycling of waste plastics from car wrecks.</a><br>

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2008

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Applied Polymer Science

  • ISSN

    0021-8995

  • e-ISSN

  • Volume of the periodical

    109

  • Issue of the periodical within the volume

    1

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    8

  • Pages from-to

    226-233

  • UT code for WoS article

  • EID of the result in the Scopus database