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Novel fluorene - thiophene copolymers synthesis, photophysical and electrochemical properties

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F08%3A00310156" target="_blank" >RIV/61389013:_____/08:00310156 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Novel fluorene - thiophene copolymers synthesis, photophysical and electrochemical properties

  • Original language description

    Novel alternating fluorene - thiophene copolymers, F3HT, FIPT, and FPyT, consisting of 9,9-dihexylfluorene and 3-substituted (with hexyl, 3-methylbutyl and 2-(pyren-1-yl)vinyl, respectively) thiophene units were synthesized. Photoluminescence(PL) and electrochemical behavior of these polymers were studied. Thin films of F3HT and FIPT showed an intense green PL emission whereas the PL emission of FPyT thin films was orange. The PL emission spectra in thin films differ from those measured in THF solutionsindicating that aggregate formation played an important role in the solid state.

  • Czech name

    Nové kopolymery fluorenu a thiofenu: syntéza, fotofyzikální a elektrochemické vlastnosti

  • Czech description

    Byly syntetizovány nové kopolymery (F3HT, FIPT a FPyT) sestávající se z 9,9-dihexylfluorenu a substituovaného thiofenu v poloze 3 (hexylem, 3-methylbutylem a 2-(pyren-1-yl)vinylem) a byly studovány jejich fotoluminiscenční a elektrochemické vlastnosti. Tenké vrstvy polymerů F3HT a FIPT vykazují intenzivní zelenou fotoluminiscenci zatímco vrstvy FPyT oranžovou. Rozdíly ve fotoluminiscenčních spektrech roztoků a tenkých vrstev ukazují na formování agregátů v pevné fázi.

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    BM - Solid-state physics and magnetism

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2008

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Macromolecular Symposia

  • ISSN

    1022-1360

  • e-ISSN

  • Volume of the periodical

    268

  • Issue of the periodical within the volume

    1

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    5

  • Pages from-to

    105-109

  • UT code for WoS article

  • EID of the result in the Scopus database