Synthesis of amphiphilic diblock copolymer brushes by successive RAFT polymerization of lauryl methacrylate and PEO-containing macromonomer

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F10%3A00347112" target="_blank" >RIV/61389013:_____/10:00347112 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Synthesis of amphiphilic diblock copolymer brushes by successive RAFT polymerization of lauryl methacrylate and PEO-containing macromonomer

Original language description

Reversible addition-fragmentation chain transfer (RAFT) polymerization of lauryl methacrylate (LMA) in the presence of S-methoxycarbonyl phenylmethyl dithiobenzoate (MCPDB) as a RAFT chain transfer agent (CTA) and subsequent RAFT polymerization of poly(ethylene oxide) monomethyl ether methacrylate (PEO5MEMA or PEO45MEMA) was done with the aim to prepare amphiphilic diblock copolymer brushes of controlled structure. The molecular weight of PLMA and PLMA-b-PPEO5MEMA copolymers was evaluated by several methods Several diblock copolymers PLMAb- PPEO5MEMA with various lengths of the blocks and a high molecular weight (Mn up to 300 000) were prepared and characterized. RAFT polymerization of PEO45MEMA from PLMA as a macro-CTA failed.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CD - Macromolecular chemistry

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2010

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Chemija

ISSN

0235-7216

e-ISSN

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Volume of the periodical

21

Issue of the periodical within the volume

1

Country of publishing house

LT - LITHUANIA

Number of pages

8

Pages from-to

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UT code for WoS article

000279000900010

EID of the result in the Scopus database

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