Structures and characterization of [Zn(n-chlorosalicylato)2(N-methylnicotinamide)2(H2O)2] (n = 4 or 5) ligand isomers
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F11%3A00358731" target="_blank" >RIV/61389013:_____/11:00358731 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1007/s10870-010-9898-0" target="_blank" >http://dx.doi.org/10.1007/s10870-010-9898-0</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s10870-010-9898-0" target="_blank" >10.1007/s10870-010-9898-0</a>
Alternative languages
Result language
angličtina
Original language name
Structures and characterization of [Zn(n-chlorosalicylato)2(N-methylnicotinamide)2(H2O)2] (n = 4 or 5) ligand isomers
Original language description
Two ligand isomers [Zn{4-ClC6H3-2-(OH)COO}(2)(Menia)(2)(H2O)(2)] (I) and [Zn{5-ClC6H3-2-(OH)COO}(2)(Menia)(2)(H2O)(2)] (II) (Menia = N-methylnicotinamide) were prepared and characterized by elemental analysis, IR spectroscopy and thermal analysis. Also X-ray crystal structures of complexes (I) and (II) were determined. They both crystallize in the triclinic space group P (1) over bar, differing in cell parameters. The molecular structure of both isomers is monomeric. Each Zn(II) atom is hexacoordinatedby three pairs of unidentate ligands in trans-positions (ZnO4N2). The 5-Clsal complex is somewhat less distorted than 4-Clsal complex (Cl-sal = chlorosalicylate). The structural data are compared with those found in a similar compound [Zn(RCOO)(2)(NL)(2)(H2O)(2)].
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Chemical Crystallography
ISSN
1074-1542
e-ISSN
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Volume of the periodical
41
Issue of the periodical within the volume
4
Country of publishing house
US - UNITED STATES
Number of pages
6
Pages from-to
443-448
UT code for WoS article
000288178600002
EID of the result in the Scopus database
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