Solid-state oxidation of aniline hydrochloride with various oxidants

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F11%3A00360780" target="_blank" >RIV/61389013:_____/11:00360780 - isvavai.cz</a>

Alternative codes found

RIV/00216208:11320/11:10104624

Result on the web

<a href="http://dx.doi.org/10.1016/j.synthmet.2011.04.037" target="_blank" >http://dx.doi.org/10.1016/j.synthmet.2011.04.037</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.synthmet.2011.04.037" target="_blank" >10.1016/j.synthmet.2011.04.037</a>

Result language

angličtina

Original language name

Solid-state oxidation of aniline hydrochloride with various oxidants

Original language description

Aniline hydrochloride was oxidized in the solid state with three different oxidants. Polyaniline salt was obtained after a few hours when ammonium peroxydisulfate was used as an oxidant. The polymerization of aniline hydrochloride with silver nitrate leads to polyaniline only after several days; in the case of iron(III) chloride, aniline oligomers were obtained. The conductivity of the polyaniline was 0.21 S cm1 when ammonium peroxydisulfate was applied; it is comparable with the conductivity of a standard? polyaniline. The oxidation with silver nitrate yields a composite material, polyaniline salt and silver particles, with conductivity 1.5 103 S cm1. Photoacoustic spectroscopy was employed to study the kinetics of the oxidation reaction. Infrared andUV?vis spectra were efficient tools to characterize the final products, and to compare their molecular structure with that of the polyaniline prepared under standard? conditions in aqueous medium.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CD - Macromolecular chemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2011

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Synthetic Metals

ISSN

0379-6779

e-ISSN

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Volume of the periodical

161

Issue of the periodical within the volume

13

Country of publishing house

CH - SWITZERLAND

Number of pages

8

Pages from-to

1353-1360

UT code for WoS article

000293437100031

EID of the result in the Scopus database

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