Carbosilane Metallodendrimers with Titanocene Dichloride end Groups

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F12%3A00383459" target="_blank" >RIV/61389013:_____/12:00383459 - isvavai.cz</a>

Alternative codes found

RIV/67985858:_____/12:00383459

Result on the web

<a href="http://dx.doi.org/10.1021/om300559y" target="_blank" >http://dx.doi.org/10.1021/om300559y</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1021/om300559y" target="_blank" >10.1021/om300559y</a>

Result language

angličtina

Original language name

Carbosilane Metallodendrimers with Titanocene Dichloride end Groups

Original language description

Carbosilane metallodendrimers containing substituted titanocene dichloride end groups were prepared using hydrosilylation as the capping reaction. Two complementary pathways were followed: hydrosilylation of ?-alkenyl-substituted titanocene dichloride complexes with SiH bond terminated dendrimers and hydrosilylation of vinyl terminated dendritic materials with 3-(dimethylsilyl)propyl-substituted titanocene dichloride. The former procedure provided dendrimers of the first generation with four end units and of the second generation with eight end units. The latter method gave dendrititic wedges and dendrimers up to the second generation with 16 peripheral titanocene dichloride units and molecular weight 7070 Da. Dendritic materials were purified by GPC and characterized by MALDI-TOF mass spectrometry and ESI-TOF mass spectrometry (metallodendrimers) and also by multinuclear NMR.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CC - Organic chemistry

OECD FORD branch

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Project

<a href="/en/project/LC06070" target="_blank" >LC06070: The structure and synthetic applications of transition metal complexes</a><br>

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2012

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Organometallics

ISSN

0276-7333

e-ISSN

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Volume of the periodical

31

Issue of the periodical within the volume

19

Country of publishing house

US - UNITED STATES

Number of pages

8

Pages from-to

6779-6786

UT code for WoS article

000309488500009

EID of the result in the Scopus database

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