Carbosilane Metallodendrimers with Cyclopentadienyldichlorotitanium(IV) End Groups
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F12%3A00375563" target="_blank" >RIV/67985858:_____/12:00375563 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1007/s10904-011-9632-1" target="_blank" >http://dx.doi.org/10.1007/s10904-011-9632-1</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s10904-011-9632-1" target="_blank" >10.1007/s10904-011-9632-1</a>
Alternative languages
Result language
angličtina
Original language name
Carbosilane Metallodendrimers with Cyclopentadienyldichlorotitanium(IV) End Groups
Original language description
Dendritic polyols of the second and third generation 2G-OH8 (1), 2G-OH16 (2), and 3G-OH16 (3) were prepared by hydroboration/oxidation of allyl-terminated carbosilane dendrimers and used as supports for the immobilization of cyclopentadienyltrichlorotitanium(IV) complexes via alcoholysis. The reaction of 1 - 3 with CpTiCl3 gave metallodendrimers 2G-(OTiCpCl2)8 (4a), 2G-(OTiCpCl2)16 (5a), and 3G-(OTiCpCl2)16 (6a), respectively, whereas the reaction of 1 and 3 with CpSiFTiCl3 (CpSiF = C5H4SiMe2CH2CH2C8F17) yielded peripherally fluorinated metallodendrimers 2G-(OTiCpSiFCl2)8 (4b) and 3G-(OTiCpSiFCl2)16 (6b). The suggested structures were supported by comparison with model 1-propoxycomplexes 10a,b. To identify side products of the alcoholysis reaction, hydrolytic behavior of the starting trichloro complexes was studied both in solid state and in solution.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
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Result continuities
Project
<a href="/en/project/LC06070" target="_blank" >LC06070: The structure and synthetic applications of transition metal complexes</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Inorganic and Organometallic Polymers and Materials
ISSN
1574-1443
e-ISSN
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Volume of the periodical
22
Issue of the periodical within the volume
2
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
8
Pages from-to
470-477
UT code for WoS article
000301522300022
EID of the result in the Scopus database
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