Synthesis of non-fouling poly[N-(2-hydroxypropyl) methacrylamide] brushes by photoinduced SET-LRP

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F15%3A00445125" target="_blank" >RIV/61389013:_____/15:00445125 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1039/C5PY00506J" target="_blank" >http://dx.doi.org/10.1039/C5PY00506J</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/C5PY00506J" target="_blank" >10.1039/C5PY00506J</a>

Result language
angličtina
Original language name
Synthesis of non-fouling poly[N-(2-hydroxypropyl) methacrylamide] brushes by photoinduced SET-LRP
Original language description
Surface-initiated photoinduced single-electron transfer living radical polymerization (SET-LRP) was employed to assemble brushes of poly[N-(2-hydroxypropyl) methacrylamide] (poly(HPMA)) from silicon surfaces. The linear increase in thickness of the poly(HPMA) brushes with time and the ability to prepare block copolymers indicate the living nature of this grafting-from process. Copper concentrations as low as 80 ppb were sufficient for this surface-initiated SET-LRP. Micropatterns of poly(HPMA) brushes on the silicon surface were constructed for the first time by this method. Negligible fouling was observed after contact with undiluted blood plasma. This report provides the first example of non-fouling polymer brushes prepared by SET-LRP of HPMA.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CD - Macromolecular chemistry
OECD FORD branch
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Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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