Supramolecular self-assembly of novel thermo-responsive double-hydrophilic and hydrophobic Y-shaped [MPEO-b-PEtOx-b-(PCL)2] terpolymers

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F15%3A00446010" target="_blank" >RIV/61389013:_____/15:00446010 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1039/C5RA08298F" target="_blank" >http://dx.doi.org/10.1039/C5RA08298F</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1039/C5RA08298F" target="_blank" >10.1039/C5RA08298F</a>

Result language

angličtina

Original language name

Supramolecular self-assembly of novel thermo-responsive double-hydrophilic and hydrophobic Y-shaped [MPEO-b-PEtOx-b-(PCL)2] terpolymers

Original language description

Nonlinear amphiphilic block copolymer architectures with precisely controlled structures bring new challenges to biomedical materials research. The paper describes the straightforward synthesis of new ?snake tongue? Y-shaped terpolymers containing poly(ethylene oxide) (PEO), poly(2-ethyl-2-oxazoline) (PEtOx) and poly(?-caprolactone) (PCL) blocks into structure [AB(C)2] (herein referred to as [MPEO44-b-PEtOx252-b-(PCL)244], [MPEO44-b-PEtOx252-b-(PCL)287], [MPEO44-b-PEtOx252-b-(PCL)2131]). A series of well-defined Y-shaped terpolymers were successfully synthesised by a combination of living cationic and anionic ring-opening polymerization (ROP). The selected Y-shaped [MPEO44-b-PEtOx252-b-(PCL)244] terpolymer self-assembly was characterised in detail by static and dynamic light scattering, nanoparticle tracking analysis and cryo-transmission electron microscopy. The physico-chemical properties as well as the molecular architecture effect on the self-assembled structures and on the LCST we

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CD - Macromolecular chemistry

OECD FORD branch

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Project

Result was created during the realization of more than one project. More information in the Projects tab.

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2015

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

RSC Advances

ISSN

2046-2069

e-ISSN

—

Volume of the periodical

5

Issue of the periodical within the volume

77

Country of publishing house

GB - UNITED KINGDOM

Number of pages

11

Pages from-to

62844-62854

UT code for WoS article

000358620100063

EID of the result in the Scopus database

2-s2.0-84938223470