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Heterogeneity of accelerated photooxidation in stabilized bulk commodity polymers studied by X-band ESRI

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F18%3A00495543" target="_blank" >RIV/61389013:_____/18:00495543 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1007/s00723-018-1042-x" target="_blank" >http://dx.doi.org/10.1007/s00723-018-1042-x</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1007/s00723-018-1042-x" target="_blank" >10.1007/s00723-018-1042-x</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Heterogeneity of accelerated photooxidation in stabilized bulk commodity polymers studied by X-band ESRI

  • Original language description

    Heterogeneity of photooxidation processes in plaques made of commodity polymers, high-density polyethylene, and cyclic olefin copolymer poly(ethylene-co-norbornene) (Topas® 8007) stabilized with various hindered amine stabilizers. Some of them in combination with UV stabilizers exposed to accelerated weathering were studied using electron spin resonance imaging (ESRI) and three independent microscopic-scale methods: scanning electron microscopy, infrared microscopy, and microhardness testing. Concentration profiles of nitroxides mapping photooxidation process inside polymer plaques along the direction of incident radiation (perpendicular to the irradiated surface of the plaques) were determined by ESRI technique in dependence on the duration of the accelerated photooxidation. ESRI data were complemented with profiles of oxidation products, crystallinity, and microhardness measured inside the plaques along the same direction. Selection of stabilizers in the study was completed with α-tocopherol that is considered as the most active component of excellent processing stabilizer vitamin E.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10404 - Polymer science

Result continuities

  • Project

    <a href="/en/project/LM2015064" target="_blank" >LM2015064: Czech National Node to the European Infrastructure for Translational Medicine</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2018

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Applied Magnetic Resonance

  • ISSN

    0937-9347

  • e-ISSN

  • Volume of the periodical

    49

  • Issue of the periodical within the volume

    11

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    18

  • Pages from-to

    1217-1234

  • UT code for WoS article

    000448720400005

  • EID of the result in the Scopus database

    2-s2.0-85050638743