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Heterogeneity of accelerated photooxidation in commodity polymers stabilized by HAS: ESRI, IR, and MH study

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F14%3A00427368" target="_blank" >RIV/61389013:_____/14:00427368 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1016/j.polymdegradstab.2014.02.019" target="_blank" >http://dx.doi.org/10.1016/j.polymdegradstab.2014.02.019</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.polymdegradstab.2014.02.019" target="_blank" >10.1016/j.polymdegradstab.2014.02.019</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Heterogeneity of accelerated photooxidation in commodity polymers stabilized by HAS: ESRI, IR, and MH study

  • Original language description

    Heterogeneity of the photooxidation processes in plaques made of four commodity polymers, polypropylene (PP), polyethylene (PE), polystyrene (PS) and poly(ethylene-co-norbornene) (Topas, TP) stabilized with hindered amine stabilizer (HAS) were studied using Electron Spin Resonance Imaging (ESRI) and three independent microscopic-scale methods: scanning electron microscopy (SEM), infrared microscopy (IR) and microhardness (MH). Concentration profiles of nitroxides mapping photooxidation process inside polymer plaques along the direction perpendicular to their surface were determined by electron spin resonance imaging technique (ESRI) in dependence on the duration of accelerated photooxidation. We present data characterizing stabilization activity of Chimassorb 119, Chimassorb 944, Tinuvin 770 in combination with UV stabilizer Tinuvin 320 or Tinuvin 327, nitroxide HAS Prostab 5415, and alkoxyamine derivative of HAS Tinuvin NOR 371 and compare them with the previously published data. Comp

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    BO - Biophysics

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA202%2F09%2F2078" target="_blank" >GA202/09/2078: Bioinspired nanoparticles sensitive to environment stimuli</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2014

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Polymer Degradation and Stability

  • ISSN

    0141-3910

  • e-ISSN

  • Volume of the periodical

    103

  • Issue of the periodical within the volume

    May

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    15

  • Pages from-to

    11-25

  • UT code for WoS article

    000336006300002

  • EID of the result in the Scopus database