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Chitosan/polyaniline hybrid for the removal of cationic and anionic dyes from aqueous solutions

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F19%3A00497234" target="_blank" >RIV/61389013:_____/19:00497234 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216208:11310/19:10388095

  • Result on the web

    <a href="https://onlinelibrary.wiley.com/doi/full/10.1002/app.47056" target="_blank" >https://onlinelibrary.wiley.com/doi/full/10.1002/app.47056</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/app.47056" target="_blank" >10.1002/app.47056</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Chitosan/polyaniline hybrid for the removal of cationic and anionic dyes from aqueous solutions

  • Original language description

    Nanostructured chitosan/polyaniline (CH/PANI) hybrid was synthesized via in situ polymerization of aniline in the presence of chitosan. The CH/PANI hybrid was characterized by FTIR spectroscopy, X‐ray diffraction, thermogravimetric analysis, and scanning electron microscopy. The CH/PANI hybrid had a nanofibrous structure with an average diameter of 70 nm. This hybrid was employed as an ecofriendly and efficient adsorbent with high adsorption capacity for the removal of Acid Green 25 (AG) and methylene blue (MB) from aqueous solutions. AG and MB were used as anionic and cationic model dyes, respectively. The CH/PANI adsorbent showed high dependence on the pH of the medium with an excellent adsorption performance and regeneration manner. The kinetics and adsorption isotherms were studied. The CH/PANI hybrid follows the pseudo second‐order adsorption kinetics and Temkin isotherm model for the adsorption of both AG and MB dyes. This assumes that the enthalpy of dyes molecules decreases with the adsorption on heterogeneous surface with various kinds of adsorption sites and as well as the ability to form multilayers of the dye. Also, intraparticle diffusion was found to play an important role in the adsorption mechanism. The maximum adsorption capacity was found to be 240.4 mg g−1 of AG at pH 4 and 81.3 mg g−1 of MB at pH 11.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10404 - Polymer science

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2019

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Applied Polymer Science

  • ISSN

    0021-8995

  • e-ISSN

  • Volume of the periodical

    136

  • Issue of the periodical within the volume

    6

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    12

  • Pages from-to

    1-12

  • UT code for WoS article

    000451334300011

  • EID of the result in the Scopus database

    2-s2.0-85052968865