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Eco-Friendly and Economic, Adsorptive Removal of Cationic and Anionic Dyes by Bio-Based Karaya Gum-Chitosan Sponge

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989592%3A15640%2F21%3A73607157" target="_blank" >RIV/61989592:15640/21:73607157 - isvavai.cz</a>

  • Alternative codes found

    RIV/46747885:24620/21:00008190

  • Result on the web

    <a href="http://www.mdpi.com/journal/polymers" target="_blank" >http://www.mdpi.com/journal/polymers</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.3390/polym13020251" target="_blank" >10.3390/polym13020251</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Eco-Friendly and Economic, Adsorptive Removal of Cationic and Anionic Dyes by Bio-Based Karaya Gum-Chitosan Sponge

  • Original language description

    A novel, lightweight (8 mg/cm(3)), conjugate sponge of karaya gum (Kg) and chitosan (Ch) has been synthesized with very high porosity (similar to 98%) and chemical stability, as a pH-responsive adsorbent material for the removal of anionic and cationic dyes from aqueous solutions. Experimental results showed that Kg-Ch conjugate sponge has good adsorption capacity for anionic dye methyl orange (MO: 32.81 mg/g) and cationic dye methylene blue (MB: 32.62 mg/g). The optimized Kg:Ch composition grants access to the free and pH-dependent ionizable functional groups on the surface of the sponge for the adsorption of dyes. The studies on the adsorption process as a function of pH, adsorbate concentration, adsorbent dose, and contact time indicated that the adsorption capacity of MB was decreased with increasing pH from 5 to 10 and external mass transfer together with intra-particle diffusion. The adsorption isotherm of the anionic dye MO was found to correlate with the Langmuir model (R-2 = 0.99) while the adsorption of the cationic MB onto the sponge was better described by the Freundlich model (R-2 = 0.99). Kinetic regression results specified that the adsorption kinetics were well represented by the pseudo-second-order model. The H-bonding, as well as electrostatic interaction between the polymers and the adsorption interactions of dyes onto Kg-Ch sponge from aqueous solutions, were investigated using attenuated total reflection-Fourier transform infrared (ATR-FTIR) spectroscopy, and the highly wrinkled porous morphology was visualized in depth by field-emission scanning electron microscopy (FE-SEM) analysis. Moreover, the samples could be reused without loss of contaminant removal capacity over six successive adsorption-desorption cycles. The hierarchical three-dimensional sponge-like structure of Kg has not been reported yet and this novel Kg-Ch sponge functions as a promising candidate for the uninterrupted application of organic pollutant removal from water.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    21001 - Nano-materials (production and properties)

Result continuities

  • Project

    <a href="/en/project/LM2018124" target="_blank" >LM2018124: Nanomaterials and Nanotechnologies for Environment Protection and Sustainable Future</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2021

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Polymers

  • ISSN

    2073-4360

  • e-ISSN

  • Volume of the periodical

    2021(13)

  • Issue of the periodical within the volume

    2

  • Country of publishing house

    CH - SWITZERLAND

  • Number of pages

    21

  • Pages from-to

    1-21

  • UT code for WoS article

    000611446100001

  • EID of the result in the Scopus database

    2-s2.0-85099485674