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Electrospun PCL mats modified with magnetic nanoparticles and tannic acid with antibacterial and possible antiosteosarcoma activity for bone tissue engineering and cancer treatment

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389013%3A_____%2F25%3A00637802" target="_blank" >RIV/61389013:_____/25:00637802 - isvavai.cz</a>

  • Alternative codes found

    RIV/67985823:_____/25:00637802 RIV/44555601:13440/25:43899209 RIV/00216208:11310/25:10515588

  • Result on the web

    <a href="https://pubs.acs.org/doi/10.1021/acsbiomaterials.5c00116" target="_blank" >https://pubs.acs.org/doi/10.1021/acsbiomaterials.5c00116</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1021/acsbiomaterials.5c00116" target="_blank" >10.1021/acsbiomaterials.5c00116</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Electrospun PCL mats modified with magnetic nanoparticles and tannic acid with antibacterial and possible antiosteosarcoma activity for bone tissue engineering and cancer treatment

  • Original language description

    Modifying scaffolds with agents that at the same time positively influence osteogenic cells and have a negative impact on cancerous growth, is a promising solution for patients with bone tissue defects following tumor excision. Such materials may not only boost tissue regeneration but also limit the risk of cancer reoccurrence. In our study, we developed novel bifunctional scaffolds containing magnetic nanoparticles grafted with PCL (MNP@PCL) and tannic acid (TA), which may be directed to support normal bone cells and suppress osteosarcoma cells. First, MNPs were postsynthetically surface-modified, by grafting poly(ε-caprolactone) (PCL) from the surface via ring opening polymerization of ε-caprolactone, to provide their uniform distribution within the polymer matrix. Then, fiber mats containing a fixed amount of MNPs (2 wt %) and increasing content of TA (0, 1, 5, and 10 wt %) were prepared by electrospinning method. Both MNP@PCL and TA decreased polymer crystallinity. The interaction between the MNPs and TA significantly influenced the mat morphology, thermal properties, and initial hydrolytic performance. The most intensive TA release was observed mainly within first 6 h of incubation, and it was 3.5-fold higher (ca. 0.02 mg of TA/per mg of mat) for mfPCL@TA-10 compared to mfPCL@TA-5. Moreover, TA-containing magnetic mats suppressed the metabolic activity of osteosarcoma cells. They also demonstrated enhanced antimicrobial properties against the bacteria typically accompanying orthopedic complications, reducing the population of Gram-positive bacteria by more than 90% compared to the neat PCL mat. This proves the high potential of these materials for combining cancer treatment with bone tissue engineering.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10404 - Polymer science

Result continuities

  • Project

    <a href="/en/project/GA20-07015S" target="_blank" >GA20-07015S: Magnetic Composite Materials for Non-Invasive Cell Stimulation in Tissue Engineering</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2025

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    ACS Biomaterials Science & Engineering

  • ISSN

    2373-9878

  • e-ISSN

    2373-9878

  • Volume of the periodical

    11

  • Issue of the periodical within the volume

    7

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    16

  • Pages from-to

    4315-4330

  • UT code for WoS article

    001517659500001

  • EID of the result in the Scopus database

    2-s2.0-105009257738