Latest Developments of the Julia-Kocienski Olefination Reaction: Mechanistic Considerations
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389030%3A_____%2F24%3A00600477" target="_blank" >RIV/61389030:_____/24:00600477 - isvavai.cz</a>
Alternative codes found
RIV/61989592:15310/24:73627766
Result on the web
<a href="https://doi.org/10.3390/molecules29122719" target="_blank" >https://doi.org/10.3390/molecules29122719</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.3390/molecules29122719" target="_blank" >10.3390/molecules29122719</a>
Alternative languages
Result language
angličtina
Original language name
Latest Developments of the Julia-Kocienski Olefination Reaction: Mechanistic Considerations
Original language description
Since its discovery, the Julia-Kocienski olefination reaction has over past 30 years become one of the key C-C connective methods that is used in late-stage natural product synthesis. The reaction proceeds under mild reaction conditions, with a wide substrate scope and functional group tolerance range and with high (E) selectivity. In this focused review, we discuss the reaction from a mechanistic point of view and disclose key features that play an important role in reaction selectivity. Finally, the mechanistic aspects of the newly developed modification of the Julia-Kocienski reaction, which allows the formation of both (E) and (Z) olefins from the same reaction partners, are discussed.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
—
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2024
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Molecules
ISSN
1420-3049
e-ISSN
1420-3049
Volume of the periodical
29
Issue of the periodical within the volume
12
Country of publishing house
CH - SWITZERLAND
Number of pages
19
Pages from-to
2719
UT code for WoS article
001255992700001
EID of the result in the Scopus database
2-s2.0-85197139473