Julia-Kocienski-Like Connective C−C and C=C Bond-Forming Reaction

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61389030%3A_____%2F24%3A00587192" target="_blank" >RIV/61389030:_____/24:00587192 - isvavai.cz</a>
Alternative codes found
RIV/61989592:15310/24:73626663
Result on the web
<a href="https://doi.org/10.1002/adsc.202301054" target="_blank" >https://doi.org/10.1002/adsc.202301054</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/adsc.202301054" target="_blank" >10.1002/adsc.202301054</a>

Result language
angličtina
Original language name
Julia-Kocienski-Like Connective C−C and C=C Bond-Forming Reaction
Original language description
In this paper, we present a one-pot protocol that enables a straightforward and selective transformation of alkyl benzothiazol-2-yl and phenyltetrazol-2-yl sulfones and acyl chlorides into ketones, E-olefins, Z-olefins, and even pyrroles. The final product of the reaction depends on the proper choice of the reaction workup. Notably, the protocol designed for olefin formation allows a switch between E- and Z-olefin formation by the correct choice of the reaction workup. These developed protocols facilitate the formation of all compounds under mild reaction conditions, as evidenced by the synthesis of (nitro)-fatty acids, and the concept can be extended to other product formations, as demonstrated by the synthesis of pyrroles.
Czech name
—
Czech description
—

Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
—
OECD FORD branch
10401 - Organic chemistry

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2024
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)