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The experience with flue-gas desulphurization by ammonium

Result description

Desulphurization by ammonium is an alternative to limestone method for desulphurization of flue gas. We have experimentally verified that the oxidation reaction can be sufficiently accelerated with ferric oxide, which act as an oxygen transmitter. The reaction must proceed at an equimolar ratio of SO2/NH3. The solution pH is lower than 4. It has been experimentally proven that the addition of ammonium can decrease the content of SO2 from 900 -1000 mg/Nm3 (at 4 ? 5% vol. content of oxygen in fuel gas) tothe value below 100 mg SO2/Nm3. HCl, HF and NO2 will be eliminated at the same time. The concentration of ammonium salts in fuel gas has not exceeded 10 mg NH3/Nm3.

Keywords

desulphurizationammoniumabsorption

The result's identifiers

Alternative languages

  • Result language

    angličtina

  • Original language name

    The experience with flue-gas desulphurization by ammonium

  • Original language description

    Desulphurization by ammonium is an alternative to limestone method for desulphurization of flue gas. We have experimentally verified that the oxidation reaction can be sufficiently accelerated with ferric oxide, which act as an oxygen transmitter. The reaction must proceed at an equimolar ratio of SO2/NH3. The solution pH is lower than 4. It has been experimentally proven that the addition of ammonium can decrease the content of SO2 from 900 -1000 mg/Nm3 (at 4 ? 5% vol. content of oxygen in fuel gas) tothe value below 100 mg SO2/Nm3. HCl, HF and NO2 will be eliminated at the same time. The concentration of ammonium salts in fuel gas has not exceeded 10 mg NH3/Nm3.

  • Czech name

  • Czech description

Classification

  • Type

    D - Article in proceedings

  • CEP classification

    JE - Non-nuclear power engineering, energy consumption and utilization

  • OECD FORD branch

Result continuities

Others

  • Publication year

    2012

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    The 4th International Conference on Engineering for Waste and Biomass Valorisation (WasteEng12) : proceedings : September 10-13, 2012 Porto. Vol 3

  • ISBN

    979-10-91526-00-5

  • ISSN

  • e-ISSN

  • Number of pages

    6

  • Pages from-to

    816-821

  • Publisher name

    Mines d'Albi

  • Place of publication

    Albi

  • Event location

    Porto

  • Event date

    Sep 10, 2012

  • Type of event by nationality

    WRD - Celosvětová akce

  • UT code for WoS article

Basic information

Result type

D - Article in proceedings

D

CEP

JE - Non-nuclear power engineering, energy consumption and utilization

Year of implementation

2012