Humic acids from oxidized coals I. Elemental composition, titration curves, heavy metals in HA samples, nuclear magnetic resonance spectra of HAs and infrared spectroscopy

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27360%2F04%3A00010171" target="_blank" >RIV/61989100:27360/04:00010171 - isvavai.cz</a>

Result on the web

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DOI - Digital Object Identifier

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Result language

angličtina

Original language name

Humic acids from oxidized coals I. Elemental composition, titration curves, heavy metals in HA samples, nuclear magnetic resonance spectra of HAs and infrared spectroscopy

Original language description

The formation of humic acids (HAs) from bituminous coal was verified by laboratory oxidation. In a relatively short time the oxidation by air at temperature above 150 °C led to the formation of HAs. These HAs were compared with those isolated from oxidized bituminous coal from the vicinity of red bed bodies, from weathered bituminous coal, oxihumolite and lignite. For this the organic and inorganic elemental composition of HAs, apparent dissociation constants, metal-binding capacities, nuclear magneticresonance and infrared spectra were determined and evaluated. With increasing temperature of laboratory oxidation of bituminous coal the percentage of aromaticity of HAs increases. HAs prepared from coal oxidized at 150 °C are characterized by an aromaticity index 78% while for HAs prepared at 250 and 300 °C by 95% aromaticity. The same index for HAs isolated from naturally oxidized bituminous coals is of about 87% whereas it is of about 50% for oxihumolite and lignite. The apparent diss

Czech name

Huminové kyseliny z oxidovaných uhlí, I. Prvkové složení titrační křivky, těžké kovy v HA vzorcích, NMR spektra huminových kyselin a infračervené spektrometrie

Czech description

Huminové kyseliny z oxidovaných uhlí, I. Prvkové složení titrační křivky, těžké kovy v HA vzorcích, NMR spektra huminových kyselin a infračervené spektrometrie

Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

DB - Geology and mineralogy

OECD FORD branch

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Project

<a href="/en/project/GA105%2F02%2F0163" target="_blank" >GA105/02/0163: The study of higher ash lignite composition on affinity and volatility of toxic elements and substances for energetic utilization</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2004

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Chemosphere

ISSN

0045-6535

e-ISSN

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Volume of the periodical

Neuveden

Issue of the periodical within the volume

54

Country of publishing house

NL - THE KINGDOM OF THE NETHERLANDS

Number of pages

9

Pages from-to

1237-1245

UT code for WoS article

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EID of the result in the Scopus database

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