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Determination of cetyltrimethylammonium bromide by capillary isotachophoresis

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27360%2F04%3A00010197" target="_blank" >RIV/61989100:27360/04:00010197 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Determination of cetyltrimethylammonium bromide by capillary isotachophoresis

  • Original language description

    In this work, a method of capillary isotachophoresis (ITP) for the study of cetyltrimethylammonium bromide (CTMB) sorption on various clays1 was developed. CTMB represents cationic surfactants that have detrimental effects to aquatic organisms and must be removed from water environment2. The used leading electrolytes (LE) consisted of 5 mM potassium hydrogen carbonate and acetic acid (pH=4.5). The terminating electrolytes (TE) contained 5 mM ß-alanine and acetic acid (pH=4.0). The concentrations of CTMBin used aqueous solutions were bellow its critical micelle concentration, i.e., ca. 0.7 mM.Adsorption of CTMB to the ITP separation compartment was prevented by non-ionic polymers, such as hydroxyethylcellulose (HEC), polyvinylalcohol (PVA), and polyvinylpyrrolidone (PVP), which were dissolved in LE. They decrease the ?-potentials of the capillary walls3. When using HEC, the zones of CTMB monomers and also micelles were recorded as a result of the ITP concentration effect4. However, in

  • Czech name

    Stanovení cetyltrimethylammonium bromidu kapilární izotachoforézou

  • Czech description

    Stanovení cetyltrimethylammonium bromidu kapilární izotachoforézou

Classification

  • Type

    D - Article in proceedings

  • CEP classification

    DD - Geochemistry

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA104%2F02%2F1464" target="_blank" >GA104/02/1464: Bentonite interactions with the environment - the effect of geological history and actual conditions; use in active waste deep repositories</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2004

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    Chemické listy

  • ISBN

    0009-2770

  • ISSN

  • e-ISSN

  • Number of pages

    1

  • Pages from-to

    604

  • Publisher name

    Česká společnost chemická (ČSCH), VŠCHT Praha a ČZU Praha

  • Place of publication

    Praha

  • Event location

    Ostrava

  • Event date

    Sep 6, 2004

  • Type of event by nationality

    EUR - Evropská akce

  • UT code for WoS article