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Fluorescence study of reduced charge montmorillonite complexes with cationic dyes.

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F61989100%3A27360%2F09%3A00022150" target="_blank" >RIV/61989100:27360/09:00022150 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Fluorescence study of reduced charge montmorillonite complexes with cationic dyes.

  • Original language description

    Series of montmorillonites (M) with reduced charge (RCM) were prepared by Li+ saturation of montmorillonite and subsequently by heating at temperatures 40, 130 and 210oC. The cation exchange capacity (CEC) and X-ray diffraction pattern (d001) of RCMs were measured. The decrease of CEC and d001 was found out with decreasing charge of RCM, i.e. increasing temperature of RCM preparation. The RCM samples were intercalated by cationic dyes, especially methylene blue (MB). The fluorescence spectra of these complexes (dye/RCM) were studied. In the fluorescence spectra the significant increase of intensity was observed with decreasing of RCM charge, dye loading and with decrease of methylene blue concentration in equilibrium aqueous solution. The fully intercalated MB/RCM complexes have the fluorescence intensity very poor whereas the MB/RCM complexes with low dye loading (about 10 %) indicate much higher intensity. That was proved for next two non laser cationic dyes (Crystal violet and Nile

  • Czech name

  • Czech description

Classification

  • Type

    D - Article in proceedings

  • CEP classification

    CF - Physical chemistry and theoretical chemistry

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2009

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Article name in the collection

    Slovenský časopis o chémii pre chemické vzdelávanie, výskum a priemysel

  • ISBN

  • ISSN

    1336-7242

  • e-ISSN

  • Number of pages

    1

  • Pages from-to

  • Publisher name

    Slovenská chemická spoločnosť

  • Place of publication

    Bratislava

  • Event location

    Tatranské Matliare

  • Event date

    Sep 7, 2009

  • Type of event by nationality

    EUR - Evropská akce

  • UT code for WoS article